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- 19.40 Propose an efficient synthesis for each of the following transformations: ۵-۵ ۵-۵۰ (a) (c) (e) (9) EtO. OEt می شود (b) لمه mo-od ه - هل (d) OH OH (f)19.69 Propose an efficient synthesis for each of the following transformations: (a) (b) (c) Br Br -C MeO OMe19.73 Propose an efficient synthesis for each of the following transformations: (f) Br H
- 19.73 Propose an efficient synthesis for each of the following transformations: (d) OH -CN 0-0 Q-8" (e)19.54 Predict the major product(s) from the treatment of acetone with the following: (d) [H], (CH3)2NH, (-H2O) (e) [H], NH2NH2, (-H2O) (f) [H], NH2OH, (-H2O) (g) NaBH4, MeOH (h) RCO3H (i) HCN, KCN (j) EtMgBr followed by H₂O (k) (C6H5)3P=CHCH2CH3 (1) LIAIH, followed by H2O22.35 Propose an efficient synthesis for each of the following compounds using the malonic ester synthesis: R-x (a) (d) OH OH OH Гафон (b) (c) COEF OH +2Br COEF (e)
- 22.1 Which of the compounds shown below has the fewest a- hydrogens? (a) H 여 (b) (c) (d)18.20 Write a stepwise mechanism for each of the following reactions. (a) O H (c) O HOG NaOH, H₂O -A NaOH, H₂O d of Plz solve all parts within 30-40 I'll upvote your answer (b) CH3 H NaOD D₂O you bou H D CH3 O Then sh18.26 Predict the products of the following ether cleavage reactions: LOCH CH3 OC(CH3)3 (a) HI CF3CO,H, ? (b) H2O HI HI (c) Н,С— СНОСH,CH, (d) (CH3);CCH,OCH,CH3 H20 H2O
- 21.30 Identify the reagents necessary for each of the following transformations: (a) (b) CI Br CN OH15.37 Write mechanisms that account for the products of the following reactions: موية OH HA (-H₂O) HA (b)A key step in the synthesis of the narcotic analgesic meperidine (tradename Demerol) is the conversion of phenylacetonitrile to X. (a) What isthe structure of X? (b) What reactions convert X to meperidine ?
