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- Add Ink to Ink to Drawing Canvas Pen Shape Math Comvert Insert CHICHOBENICOCE 2 3C S 13 15 16 (Complete the mind map given Observation: veddish brown of Brs deolounzed -Br Br CH,CI, Br2, H20 Cl2, CIA HBr H;C H,O, H,o H2, Pt conc. H,SO, H2C CH CHS он dilute KMno . OH- heat 4+ CH2 CH2 HCI + mn Oz HCI, H,O Her, CH,0OCH, observation: purple cSlour Br, CI, Cl,, H,O dikúte H, So, 5 yvees ENG USProvide the following from NBS and under UV light: N-Br hv. CCI, D. B. Br A. Br Br Br O a. choice A. O b. choice B. Oc. choice C. O d. choice D.24. Which of the following steps involves umpolung? а. 1. LIAIH4 2. Но* Но H b. Cul 2 Li CULI с. Br NaOCH3 d. 1. P(C,H5)3 2. NaH Br е. H2 Pt
- 2 3 5 [Review Topics] Reagents HBr a. b. C. H₂O, H₂SO4 d. Br₂ Cl₂ H₂, Pd Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 e. f. g. h. i. j. k. I. [References] HBr, H₂O2, hv Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O2, NaOH O3 then (CH3)2S m. n. O. p. q. r. S. t. u. V. 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 H₂SO4, HgSO4 (sia)2BH then H₂O₂, NaOH 1 equivalent of NaNH2 NBS, hv Br₂, hv Cl₂, hv HCI Identify the reagents necessary to accomplish the following steps in the above synthesis of 3-hexanone from acetylene: Step 4: v Step 5: F Step 7: Previous Next Save and Exit2.F. 2.G. 2.H. diene + R2BH diene + BH3 RBH 2 H H B. B. A s + BH3 RBH2 9-BBN Page 3 of 425. ? (3,3.sigmatropic RR.) CHO 3. B. e. A. CHO OCHy Bonus ? (firal product) A. В. C.
- 19. What would be the splitting of the indicated hydrogen (s)? Choices may be used more than once IV. III. V. l l A. B. ele C. elle D. E. F. G.Rank the following according to DECREASING reactivity towards E2: Br H,C CH, Br H. CH, Br H,C. CH Br CH H. H.C CH, H. H. H. H. CH H. H. GHI JKL MNO POR Ist (most reactive) Choose 2nd Choose 3rd Choose 4th (least reactive) Choose. cofthe folowing s the correct IURAC rame.of.the compouna be oV. vi. vii. viii. ix. X. xi. xii. Boc CO₂Et NH₂ CHCI 3 KOH Pd(PPH3)4 Cul, i-Pr₂NH MezNH MgCl2 H3C. -TIPS Br₂ ACOH i. LDA ii. PhCHO iii. H₂O MeO₂C heat i. LTMP ii. H₂O -CO₂Me t-BuLi i. Zn ii. Ph 200 °C Br
- Which of the tollawing statements regarding IR spectroscopy, is wrong? a. Melecular vibrations are due to periodic metions of atoms in molecules and include bond stretching, torsional shanges, and bond angle shanges. b. intrared spectra give intormation about bonding features and functional groups in melecules С. Jntrared radiation is higher in energy, than UV radiation. d. Jatrared spectra recard the transmission of IR radiation. e.l None of the aboveSelect the correct configurational descriptor for the following: HO.,, H, CH3 II H. HO © GMU 2020 B. R C. cis D. trans E. E F. SBr -OCCCH3)3 а. b. -OCH,CH3 CI CI C. -NH2 (2 equiv)