Add curved arrows to show the next step, formation of a peroxy radical by coupling with O2, and modify the given structure to draw the resulting intermediate. Br + CH3 Edit Drawing Br. CH3
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- 3. The following three SNAR transformations follow different mechanisms. Draw an intermediate or transition state for each reaction that relates the correct mechanism. Write a short sentence as to why that is the correct intermediate for the reaction. Reaction 1: Reaction 2: NO2 NO2 NO₂ + NaOMe NO2 + NaOH2 1. aq NaHCO3. 100 C 2. H₂O+ OMe NO2 NO₂ OH ŇO₂ NO2 Reaction 3: CFa Br CF3 8--2 + NaNH2 NH3 NH₂ Intermediate/transition state Intermediate/transition state Intermediate/transition state2. Did the following overall reaction occur by an SN1 or SN2 mechanism? Explain the answer you gave in complete sentences. Draw the complete mechanism (curved arrows) to account for the formation of both products. 4 Br CH3 OH d mo Isnove tugines to win H₂C" + Orodispar J H₂Cb eldgosbourers baob OOne of the steps in the mechanism of the above reaction as shown below. Draw the structure of all the products of this reaction. com/mm/takeAssignCourt Rotivity.do?locator assignment-take 1 pt ment Eto O Eto O 3. NaOH, H₂O, heat 4. HCI, H₂O, heat One of the steps in the mechanism of the above reaction is shown below. Draw the structure of all of the products of this reaction. O OEt O 1. Eto Na 2 Å OH You do not have to consider stereochemistry. • Draw enolate anions in their carbanion form. . You should include all products. Ôno P Ć [References) . Include counter-ions, e.g., Na, I, in your submission, but draw them in their own separate sketcher. . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. . Separate multiple products using the + sign from the drop-down menu. ///-000- IF Previous Email Instructor
- What would be the final products for the reaction shown below? provide the complete mechanism for product formation. Show all intermediates and resonance structures. H₂O° H2O (excess)SECTION 6: Show the mechanism of each reactions with arrows and intermediates form as in a. b. C. HBr Br₂ Cl₂, H₂O Br Br CI Br OH2. Provide the mechanism for the reaction illustrated below. Show the relevant intermediate/transition state. Br N2OH
- 6. Complete reaction scheme below indicating reagents, catalysts and conditions, and side product trigil bezinslog si6101fon 290b 1l (b Senines levirba 6 gaubong nasamots gniwollot ads to doinW 01 sniowl (6 CH3 40 CH3 Scansgowi (d Ege nodie) ( nsgyxo (b NO₂ 19m02 2i gniwollet sits to mainW II HOProvide the mechanism for the following reaction. Eto OEt 1. Na+OEt- 2. PhMgBr 3. H₂O*, heat -CH₂- -OHSuggest a reasonable mechanism for the reaction shown Br here. HO CH;CH,OH
- Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- Rate = k [CH3CH2Br][CH3COO-] Which mechanism would best fit the data?3. For questions "A"- "C", complete the following reaction schemes (no mechanisms required). Show all reagents used in the order of application. th A) 6 B) ||| Ins HO HOStep 4a: Classify step. The target product is present, but the reaction is not over. The ethoxide ion has been regenerated. :0: :0: What is the key process in the next step of the mechanism? proton transfer formation of a o bond between nucleophile and electrophile loss of a leaving group carbocation rearrangement (e.g., methyl or hydride shift)
