Answered: Draw a reasonable, stepwise…

Draw a reasonable, stepwise arrow-pushing mechanism for the formation of the product. Make sure to account for the role of the nitro group. H KOH, H₂O NO₂

Chemistry for Today: General, Organic, and Biochemistry

9th Edition

ISBN:9781305960060

Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Chapter13: Alcohols, Phenols, And Ethers

Section: Chapter Questions

Problem 13.53E: Lipoic acid is required by many microorganisms for proper growth. As a disulfide, it functions in...

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Question

Draw a reasonable, stepwise arrow-pushing mechanism for the formation of the
product. Make sure to account for the role of the nitro group.
H
KOH, H₂O
NO₂

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a) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .
a) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .
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TESTS FOR CARBOXYLIC ACIDS Materials: Test tube – 12 Test tube rack – 1 Water bath – 1 Test tube holder -1 Tripod – 1 Graduated cylinder (100mL) – 1 Crucible tong – 1 Wire gauze – 1 Round bottom flask – 1 Condenser – 1 Iron clamp – 2 Iron stand – 2 Heating mantle – 1 Chemicals: Diluted NaOH solution Acetic acid 5% NaOH soln Benzoic acid 5% NaHCO; Phenol Ferric chloride solution Tollen's reagent Procedure: A) Reaction with sodium hydroxide Place 3 ml of acetic acid into a test tube and add 2 ml of 5% NaOH. Shake and note the solubility. Repeat using 1g of benzoic acid. B) Reaction with sodium bicarbonate Place 1 ml of acetic acid into a test tube and add 1 ml of 5% NaHCO; solution. Shake and note the solubility. Repeat using 1 ml of phenol. C) Ferric chloride test Place 1 ml of acetic acid into a test tube and add 1 ml of dilute NaOH. Add 5 drops of ferric chloride solution. Boil and note the color changes. D) Tollen's test Place 1 ml of acetic acid into a test tube and add 1 ml of…
When aniline, C6H5NH2(Kb=7.41010) , reacts with a strong acid, its conjugate acid, C6H5NH3+, is formed. Calculate the pH of a 0.100 M solution of C6H5NH3+ and compare it with the pH of acetic acid (Ka=1.86105) .