draw an unsymmetrical ketone that has both kinetic and thermodynamic enolate. one side of the ketone needs to have more carbons than the other and both alpha carbons must have a hydrogen or double bond.
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draw an unsymmetrical
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- Draw the product obtained by heating each pair of ketones in a basic solution.Why is it not advisable to use aqueous hydrochloric acid in a Grignard reaction of a ketone? A) The Grignard reagent will react with the acid and cannot react with the ketone. B) The ketone will be protonated and will become unreactive. C) The ketone will form an unreactive enol. D) The Grignard reagent won't dissolve in aqueous solutionsdraw the kinetic enolate, thermodynamic enolate, kinetic enol and thermodynamic enol for the ketone. label each structure as the kinetic enolate, thermodynamic enolate, kinetic enol or thermodynamic enol
- The Stork reaction is a condensation reaction between an enamine donor and an a,ẞ-unsaturated carbonyl acceptor. The overall reaction consists of a three-step sequence of 1. formation of an enamine from a ketone. 2. Michael addition to an α,ß-unsaturated carbonyl compound, and 3. hydrolysis of the enamine in dilute acid to regenerate the ketone. Consider the Stork reaction between cyclohexanone and propenal. Draw the structure of the product of the enamine formed between cyclohexanone and dimethylamine. ચર્ચ F Correct HC, CH3 ChemDoodle 2 Draw the structure of the Michael addition product. ChemDoodle Jn (F 106 CorrectDraw the keto form of the following enol.Draw the most stable product formed in each of the reactions shown. Reaction (a) ich NaOEt, EtOH Draw the product of reaction (a). Rings Select Draw H More
- Draw the product when the two react togetherAldol condensation is a reversible reaction and in fact aldols can be transform into the starting carbonyl compounds. Complete using arrows, the following retroaldol reactionDraw a stepwise mechanism for the following reaction. The four-membered ring in the starting material and product is called a β-lactam. This functional group confers biological activity on penicillin and many related antibiotics, as is discussed in Chapter 22. (Hint: The mechanism begins with β elimination and involves only two steps.)
- 1. Draw the indicated enols/enolates of the indicated compounds. kinetic enolate thermodynamic enolate thermodynamic enol kinetic enol kinetic enolate thermodynamic enolate thermodynamic enol kinetic enolDraw a stepwise mechanism for the following reaction. The fourmembered ring in the starting material and product is called a β-lactam. This functional group confers biological activity on penicillin and manyrelated antibiotics, as is discussed in Chapter 20. (Hint: The mechanism begins with β elimination and involves only two steps.)Draw the enol intermediate and the ketone product formed in the attachedreaction.
