Nitryl chloride (NO2CI) decomposes to nitrogen dioxide (NO₂) and chlorine gas (Cl₂) according to the following mechanism (show work): 1. 2NO₂CI(g) CIO2(g)+N₂O(g)+CIO(g)(fast, k₁ represents the rate constant for the forward reaction and k-₁ the rate constant for the reverse reaction) 2. N₂O(g)+CIO2(g) NO2(g)+NOCI(g)(fast, k₂ for the forward reaction, k-2 for the reverse reaction) 3. NOCI+CIO NO2+Cl₂(slow, k3 the rate constant for the forward reaction) Determine the overall reaction, Identify any intermediates, and determine the overall rate law expression.
Nitryl chloride (NO2CI) decomposes to nitrogen dioxide (NO₂) and chlorine gas (Cl₂) according to the following mechanism (show work): 1. 2NO₂CI(g) CIO2(g)+N₂O(g)+CIO(g)(fast, k₁ represents the rate constant for the forward reaction and k-₁ the rate constant for the reverse reaction) 2. N₂O(g)+CIO2(g) NO2(g)+NOCI(g)(fast, k₂ for the forward reaction, k-2 for the reverse reaction) 3. NOCI+CIO NO2+Cl₂(slow, k3 the rate constant for the forward reaction) Determine the overall reaction, Identify any intermediates, and determine the overall rate law expression.
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.84P
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Transcribed Image Text:Nitryl chloride (NO2₂CI) decomposes to nitrogen dioxide
(NO₂) and chlorine gas (Cl₂) according to the following
mechanism (show work):
1. 2NO₂Cl(g) CIO2(g) +N₂O(g)+CIO(g)(fast, k₁ represents
the rate constant for the forward reaction and k-₁ the
rate constant for the reverse reaction)
2. N₂O(g)+CIO2(g) NO2(g)+NOCI(g)(fast, k₂ for the
forward reaction, k-2 for the reverse reaction)
3. NOCI+CIO NO2+Cl₂(slow, k3 the rate constant for
the forward reaction)
Determine the overall reaction, Identify any
intermediates, and determine the overall rate law
expression.
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