Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 15 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 2. (CH3)2S Br2 CH₂OH 20 19 18 17 16 15 14 13 12 11 10 H₂ Pd or Pt (catalyst) Br 12 HBr ROOR (peroxide) Br2 H₂O BH3⚫THF Bra SIOH Pd or Ni (catalyst) D₂ (deuterium) Н20 H₂SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br₂ A B с D A B C D ة.
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 15 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 2. (CH3)2S Br2 CH₂OH 20 19 18 17 16 15 14 13 12 11 10 H₂ Pd or Pt (catalyst) Br 12 HBr ROOR (peroxide) Br2 H₂O BH3⚫THF Bra SIOH Pd or Ni (catalyst) D₂ (deuterium) Н20 H₂SO4 HCI 1. BH3⚫THF 2. H₂O2, NaOH Br₂ A B с D A B C D ة.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Question 15
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
(CH3)2S
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
Pd or Pt (catalyst)
20 1 2
19
18
17
16
15
14
13
12 11 10
MCPBA
1. OsO4
2. H₂O₂
CH3CO₂H
(peroxyacid)
MCPBA
HBr
ROOR (peroxide)
H₂O
H2SO4
HCI
1. BH3.THF
2. H₂O2, NaOH
Br2
Br2
H₂O
BH3⚫THF
Br2
FIOH
Pd or Ni (catalyst)
D₂ (deuterium)
A
B
с
000
ABCD
....O
D](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5ee18d23-dabe-4d3f-9a28-d765d4d29ad5%2Ff6c75c40-ee1b-492c-b86e-84f289c74b55%2F5nz22dd_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Question 15
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
(CH3)2S
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
Pd or Pt (catalyst)
20 1 2
19
18
17
16
15
14
13
12 11 10
MCPBA
1. OsO4
2. H₂O₂
CH3CO₂H
(peroxyacid)
MCPBA
HBr
ROOR (peroxide)
H₂O
H2SO4
HCI
1. BH3.THF
2. H₂O2, NaOH
Br2
Br2
H₂O
BH3⚫THF
Br2
FIOH
Pd or Ni (catalyst)
D₂ (deuterium)
A
B
с
000
ABCD
....O
D
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