This is a Dry Lab since we cannot meet on Campus. You would have first calibrated apH meter and then measured the pH of four different Acid Aqueous Solutions andexamined the data for trends. You would have calculated the expected pH of each ofthe strong acid HCI solutions by assuming that the HCI is 100% ionizedor dissociated when dissolved in water and thus Molarity HCI equals the MolarityH+. Using pH= -log H+ Molarity, the pH of a 1 X 10 to the -4 powerM HCI solution (0.0001 M) is set up as pH= -log(0.0001) = 4. Use the log function ofyour calculator to get the answer.Create a data table like this one and put your calculated HCI pH values in the table.HCI Solution Molarity: 0.1 M0.001 MExperimental pH (given) 1.20Calculated pHAnswer these questions.1. As the H+ Molarity increases what happens to the pH22. AST + Molarity inbasic?alues area pH meter.0.01 M2.153.08oreAYWhich solution is more acidic and how do you know that, based on the pHeasurements)?4. Given that the experimental pH of a 0.1 Molar Acetic Acid (CH3COOH) solution is2.89 compared to the experimental pH of 1.20 for the 0.1 Molar HCI solution,withB) Explain why the solutions are of different acidity based on the fact that in waterHCI is a strong acid whereas CH3COOH is a weak acid and their relative extent ofionization(dissociation) is quite different. A strong acid is 100% ionized to H+ and itsHA → H+. + A-. A weak acid is only ionizedconjugate base as representedslightly.

Concept: pH = -log H+ where, [H+] =Concentration of H+

This is a Dry Lab since we cannot meet on Campus. You would have first calibrated a pH meter and then measured the pH of four different Acid Aqueous Solutions and examined the data for trends. You would have calculated the expected pH of each of the strong acid HCI solutions by assuming that the HCI is 100% ionized or dissociated when dissolved in wotor

This is a Dry Lab since we cannot meet on Campus. You would have first calibrated a pH meter and then measured the pH of four different Acid Aqueous Solutions and examined the data for trends. You would have calculated the expected pH of each of the strong acid HCI solutions by assuming that the HCI is 100% ionized or dissociated when dissolved in wotor

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter16: Acids And Bases

Section: Chapter Questions

Problem 65AP: . The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in...

See similar textbooks

Similar questions

Calculate the pH of a solution prepared by mixing 49.0 mL of butyric acid, HC4H7O2, with 6.15 g of KOH in water. The following data about butyric acid may be helpful: density=0.9595g/mL;K a =1.54105
Estimate the pH that results when the following two solutions are mixed. a) 50 mL of 0.3 M CH3COOH and 50 mL of 0.4 M KOH b) 100 mL of 0.3 M CH3COOH and 50 mL of 0.4 M NaOH c) 150 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2 d) 200 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2
Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxide
Composition diagrams, commonly known as alpha plots, are often used to visualize the species in a solution of an acid or base as the pH is varied. The diagram for 0.100 M acetic acid is shown here. The plot shows how the fraction [alpha ()] of acetic acid in solution, =[CH3CO2H][CH3CO2H]+[CH3CO2] changes as the pH increases (blue curve). (The red curve shows how the fraction of acetate ion, CH3CO2, changes as the pH increases.) Alpha plots are another way of viewing the relative concentrations of acetic acid and acetate ion as a strong base is added to a solution of acetic acid in the course of a titration. (a) Explain why the fraction of acetic acid declines and that of acetate ion increases as the pH increases. (b) Which species predominates at a pH of 4, acetic acid or acetate ion? What is the situation at a pH of 6? (c) Consider the point where the two lines cross. The fraction of acetic acid in the solution is 0.5, and so is that of acetate ion. That is, the solution is half acid and half conjugate base; their concentrations are equal. At this point, the graph shows the pH is 4.74. Explain why the pH at this point is 4 74.
. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.
Consider 0.10 M solutions of the following compound: AlCl3, NaCN, KOH, CsClO4, and NaF. Place these solutions in order of increasing pH.
Two students were asked to determine the Kb of an unknown base. They were given a bottle with a solution in it. The bottle was labeled aqueous solution of a monoprotic strong acid. They were also given a pH meter, a buret, and an appropriate indicator. They reported the following data: volume of acid required for neutralization = 21.0 mL pH after 7.00 mL of strong acid added = 8.95 Use the students' data to determme the Kb of the unknown base.
Write the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. (a) sulfate ion (b) citrate ion
Consider all acid-base indicators discussed in this chapter. Which of these indicators would be suitable for the titration of each of these? (a) NaOH with HClO4 (b) acetic acid with KOH (c) NH3 solution with HBr (d) KOH with HNO3 Explain your choices.
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.