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The condition when rearrangement occurs,
The Carbocation rearrangement occurs when we get less stable carbocation to more stable carbocation.
rearrangement occurs via H-shift, alkyl shift, etc.
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- Draw all stereoisomers formed in each reaction. to [1] CH3LI а. [2] H2O 1m( Culi b. [1] [2] H2O [1] LIAIH4 С. с. [2] H2O [1] mCРBA d. [2] MgBr [3] H2O ..||which involve by migration of atom or group from k Which involve interconversion reaction. 6. anther. OA. Substation reaction. OB. Elimination reaction. OD. Addition reaction. 7. OA. Rearrangement reaction. B. Elimination reaction. C. Isomerition reaction. D. Addition reaction. C. Rearrangement reaction.5. A. B. C. D. Draw all products (substitution and elimination), including stereoisomers, in each reaction. Label as SN1, SN2, E1, E2. CI J CI & H H HCC₂ Ph ·!|||D III... Br Ph KOH CH₂OH DBU DBN
- 6. Rank order the following substitution reactions by reaction rate (Fastest to Slowest) OHS structure of DMSO A. || > | > | > IV B. II >> III > IV C. IV > II > | > ||II D. II >> IV > III E. None of the above I || III IV ~ en Br ~ Br CH,NH, CH₂OH CH₂SH DMSO CHÍNH, CH₂OH CH₂OH + Product Product Product ProductDraw the final product of this series of reactions. |||** OH 1. SOCI₂ 2. NaCN • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If more than one product is possible, only draw the major product. • If the reaction produces a racemic mixture, draw both stereoisomers.24. Which product is formed by the reaction ? A) | B) || C) ||| D) IV Br ОН NaH Br ... هستم IV
- O (1) H20, H*; (2) Jones reagent (1) H20, H*; (2) PCC, CH2CI2 (1) conc. H2SO4: (2) Jones reagent O (1) H20, H*; (2) Tollens reagent (1) conc. H2SO4: (2) PCC, CH2CI2 O (1) conc. H2SO4: (2) Tollens reagentPart A || CH2=CH' CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. Show the appropriate stereochemistry by choosing the dashed or wedged buttons and then clicking a bond on the canvas. EXP. CONT. H +) C CI Br Marvin JS [1] by O ChemAxon F P.С. (1) BH3 (2) H,O,. H,O, NaOH Product is (circle one) i. A racemic mixture ii. A single enantiomer, iii. Achiral or meso D. txt. CI Ci