7. Label each of the following structure as a reducing or nonreducing carbohydrate. CH2OH OH HO- HO. HOL CHO H- •OH H- OH HO- -H OH H- •OH CH2OH HO H- CHO H OH CH2OH HO. CH2OH HO HO CH2OH OH HO CH2OH HO CH2OH HO HO. HO CH₂OH OH HO HO. OCH3 CH2OH OH
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- Identify the glycosidic bond indicated in the following structure. CH2OH H H. OH H O. но H. OH CH2 H. H H. QH H OH H. O B-1,4-glycosidic bond O a-1,6-glycosidic bond O a-1,4-glycosidic bond O B-1,6-glycosidic bond2. Sucrose is a disaccharide formed from the condensation of glucose and fructose sugars. Draw the structure of sucrose that results from the condensation reaction between the indicated -OH groups. CH2OH 1, CH,OH он 1. OH но CH,OH OH HO H он OH1. Consider the following molecules. Clearly circle the glycosidic bond on each structure. In the Spae provided clearly describe the type of glycosidic bond illustrated. HO-CH2 O. H. H. OH HO. HO-CH2 OH H. H. H. OH H. OH Но H. H. H. OH OH HOH2Ç HO OH OH CH2OH HI エー エエー
- 10. Draw the reaction of Galactose with Benedict solution. Answer the following questions based on these structures. Here is the terminology you can use to describe the relationships. Structural isomers, Enantiomers, Diastereomers, and no relationship. CHO CHO -H H- Н- CHO HO-H OH H- НО- Н- Н- OH OH CH₂OH CHO H H -ОН -ОН но- Н- CH₂OH H -ОН CH2OH 2 Н- Н- но- НО- CHO -ОН -ОН -H -H CH2OH 8 НО Н- H- НО- -ОН -Н CH₂OH 3 CH₂OH 7 11. What is the relationship between 1 and 4? 12. What is the relationship between 1 and 3? 13. What is the relationship between 1 and 5? 14. What is the relationship between 2 and 9? Н- но 15. What is the relationship between 4 and 10? 16. What is the relationship between 5 and 6? ОН 17. What is the relationship between 2 and 10? CH2OH -ОН -Н CH2OH 9 НО- Н- Н- CH2OH :0 -H OH OH CH2OH 4 НО- НО- Н- H- но- но- CH2OH H——OH -Н -Н CH₂OH 10 H H OH OH CH₂OH 5 Н- но- но- Н- CHO -OH -H H -OH CH2OH 6Identify the anomeric carbon. Identify the glycosidic linkage. Lactose ОН ОН OH HO HO, HO OHIdentify the products of the two reactions of glucose. COOH HOH Н НО H Н HOH Н- -OH CH₂OH Н НО CH2OH -OH H- H -Н -OH OH CH₂OH Cu2+/OH- CHO O НО н H OH H-+ -OH CH₂OH Н но- Н- Н- CHO HOH но- Н- -Н -ОН H-OH CHO CHO -ОН -Н -ОН -ОН CH2OH Answer Bank 0 CH3 H— НО -OH -H H-OH H-OH CH₂OH H₂/Pt CHO H-OH HO-H H -ОН H OH COOH CH₂OH =0 HO-H H- Н -ОН -OH CH₂OH
- When Fructose (shown below) undergoes reduction in the presence of H2 and Pd, two compounds are generated. What is the relationship between the two compounds generated? ОН Но— Н H. OH H OH HO.Draw the structure of the intermediate (first product) of the following oxidation reaction. CH3CH,CH,CH,OHThe following molecule has a glycosidic bond that is best described as HỌ – CH2 НО HỌ – CH2 HO OH O ОН alpha-1,4-glycosidic bond beta-1,6-glycosidic band alpha-1,6-glycosidic bond beta-1,4-glycosidic bond ОН OH OH.H2O
- 1. What are the products of a combustion reaction? 2. Describe how the formation of these products is confirmed in the video. 3. Write the balanced equations for the combustion of the following hydrocarbons: a) Propane b) Cyclopentane c) 2-methyl-2-butene heludeWhich characteristic is shared by the ring forms of the given monosaccharides? * CH2OH CHO O= H- HO- HO- но- H- но- Но H H- -OH ČH,OH ČH2OH Both exist mainly as furanoses. Both contain a hemiacetal bond. Both can undergo mutarotation. O Both exist mainly as pyranoses.A protein is Multiple Choice о O O O о a polysaccharide. one of the units making up a nucleic acid. an aromatic hydrocarbon. a saturated ester of glycerol. a polymer of amino acids.