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- a Draw the structure of the intermediate (I) for the reaction below. Hg(O2CCH3)2 NaBH4 Product CH;OH H3C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. If the reaction produces a racemic mixture, just drawv one stereoisomer.Considering stereochemistry, draw the resulting E2 elimination product when H. is removed. H a Ho III.... H H₂ I jº ·*||||| H X Ś my èDraw the mechanism for the following reaction and account for the relative stereochemistry. MeO₂C MeO₂C CO₂Me Pd2(dba)3.CHCI 3 Ph3P, ACOH MeO₂C
- Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. 1. H3180* 2. K2CO3 Mel CH3 1. CrO3, H30* H3C HO, 2. DCC, HN A, [-H2O] HOElimination occurs when (Z)-3-bromohex-3-ene is treated with NaNH2. Under the same conditions, 1-bromocyclohexeneundergoes elimination much more sluggishly. Explain whyQ12. (1-bromoethyl)benzene 1 udergoes an elimination following an E1 mechanism. Fill in the following synthetic scheme by drawing the structure of intermediate 2 and product 3. The chemical formula of product 3 is provided as guidance. CH; RDS Br C3Hg E1 2 3
- When norbornene undergoes hydroboration-oxidation, a mixture of two stereoisomers is produced in a roughly 6:1 ratio. (a) Draw both of these isomeric products. (b) Which product is favored? Hint: You should build a model of norbornene and consider the transition state leading to each product. 1. BH3 THF ? 2. H2O2, NaOH, H,O NorborneneWhich statement best describes the stereochemistry of the product?7. Provide the synthesis for the following product starting with the provide starting material. More than one step is required. Show the mechanism for each reaction. CI- Cl- Starting Material Product