Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 10.9B, Problem 10.14P

(a)

Interpretation Introduction

To determine: The synthesis of the given secondary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods.

Interpretation: The synthesis of the given secondary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods is to be shown.

Concept introduction: The compounds in which carbonyl groups are present like ketone or aldehyde react with Grignard reagent to form alcohol.

The examples of Grignard reagent are ethyl magnesium bromide and PhMgBr.

Ether is used as the solvent in the Grignard reactions.

There are three different types of alcohols: primary, secondary and tertiary alcohol.

(b)

Interpretation Introduction

To determine: The synthesis of the given secondary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods.

Interpretation: The synthesis of the secondary primary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods is to be shown.

Concept introduction: The compounds in which carbonyl groups are present like ketone or aldehyde react with Grignard reagent to form alcohol.

The examples of Grignard reagent are ethyl magnesium bromide and PhMgBr.

Ether is used as the solvent in the Grignard reactions.

There are three different types of alcohols: primary, secondary and tertiary alcohol.

(c)

Interpretation Introduction

To determine: The synthesis of the given secondary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods.

Interpretation: The synthesis of the given secondary alcohol by adding an appropriate Grignard reagent to an aldehyde by two methods is to be shown.

Concept introduction: The compounds in which carbonyl groups are present like ketone or aldehyde react with Grignard reagent to form alcohol.

The examples of Grignard reagent are ethyl magnesium bromide and PhMgBr.

Ether is used as the solvent in the Grignard reactions.

There are three different types of alcohols: primary, secondary and tertiary alcohol.

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Chapter 10 Solutions

Organic Chemistry (9th Edition)

Ch. 10.8B - Prob. 10.11PCh. 10.8B - Prob. 10.12PCh. 10.9A - Prob. 10.13PCh. 10.9B - Prob. 10.14PCh. 10.9C - Show how you would synthesize each tertiary...Ch. 10.9D - Prob. 10.16PCh. 10.9D - Show how you would add Grignard reagents to acid...Ch. 10.9D - A formate ester, such as ethyl formate, reacts...Ch. 10.9E - Prob. 10.19PCh. 10.9E - In Section9-7B, we saw how acetylide ions add to...Ch. 10.9F - Prob. 10.21PCh. 10.10A - Prob. 10.22PCh. 10.10B - Prob. 10.23PCh. 10.11B - Predict the products you would expect from the...Ch. 10.11B - Prob. 10.25PCh. 10.11B - Prob. 10.26PCh. 10.12 - Prob. 10.27PCh. 10.12 - Prob. 10.28PCh. 10.12 - Authentic skunk spray has become valuable for use...Ch. 10 - Give a systematic (IUPAC) name for each alcohol....Ch. 10 - Give systematic (IUPAC) names for the following...Ch. 10 - Draw the structures of the following compounds...Ch. 10 - Predict which member of each pair has the higher...Ch. 10 - Predict which member of each pair is more acidic,...Ch. 10 - Predict which member of each group is most soluble...Ch. 10 - Draw the organic products you would expect to...Ch. 10 - Prob. 10.37SPCh. 10 - Show how you would synthesize the following...Ch. 10 - Show how you would use Grignard syntheses to...Ch. 10 - Show how you would accomplish the following...Ch. 10 - Show how you would synthesize the following: a....Ch. 10 - Complete the following acid-base reactions. In...Ch. 10 - Prob. 10.43SPCh. 10 - Prob. 10.44SPCh. 10 - Geminal diols, or 1,1-diols, are usually unstable,...Ch. 10 - Vinyl alcohols are generally unstable, quickly...Ch. 10 - Compound A (C7H11Br) is treated with magnesium in...Ch. 10 - Prob. 10.48SPCh. 10 - Prob. 10.49SPCh. 10 - Prob. 10.50SPCh. 10 - Prob. 10.51SPCh. 10 - Prob. 10.52SPCh. 10 - Prob. 10.53SPCh. 10 - Prob. 10.54SPCh. 10 - Prob. 10.55SPCh. 10 - Prob. 10.56SPCh. 10 - Show how this 1 alcohol can be made from the...Ch. 10 - Prob. 10.58SPCh. 10 - Prob. 10.59SPCh. 10 - Prob. 10.60SP