Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 7, Problem 7.46P
7-46 (Chemical Connections 7D) What reaction takes place when sunlight hits the compound silver chloride?
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Indicate whether the reaction is exothermic or endothermic
Cs2() + 3CI2(g) → CCI4() + S2CI2() AH° = - 112k)
The chemical reaction shown is exothermic.
CH4 + N2 + H2 → CH3N + NH3
Which statement about the reaction is correct?
The total chemical potential energy of the reactants is greater than the total chemical potential energy of the products.
More chemical potential energy is stored in the bonds of CH4 than in the bonds of CH3N.
Each reactant has more chemical potential energy than each product.
It takes more energy to form C–H bonds in the reactants than is released from C–H bonds in the products.
Chapter 7 Solutions
Introduction to General, Organic and Biochemistry
Ch. 7.1 - Problem 7-1 In the reaction we measure the...Ch. 7.4 - Problem 7-2 Calculate the rate for the reaction in...Ch. 7.6 - Prob. 7.3PCh. 7.6 - Prob. 7.4PCh. 7.6 - Prob. 7.5PCh. 7.7 - Prob. 7.6PCh. 7.7 - Problem 7-7 Consider the following equilibrium...Ch. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7 - 7-10 The rate of disappearance of HCI was measured...
Ch. 7 - 7-11 Consider the following reaction: Suppose we...Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 7.14PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 7.27PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 7.30PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 7.42PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 7.44PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - 7-64 As we shall see in Chapter 20, there are two...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 7.70PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 7.83PCh. 7 - Prob. 7.84P
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- 7-16 A quart of milk quickly spoils if left at room temperature but keeps for several days in a refrigerator. Explain.arrow_forward7-69 Pure carbon exists is several forms, two of which are diamond and graphite. The conversion of the diamond form to the graphite form is exothermic to a very slight extent. How is it that jewelers can advertise "Diamonds are forever"?arrow_forward7-43 (Chemical Connections 7A and 7B) Why is a high fever dangerous? Why is a low body temperature dangerous?arrow_forward
- 7-45 (Chemical Connections 7C) A painkiller—for example, Tylenol—can be purchased in two forms, each containing the same amount of drug. One form is a solid coated pill, and the other is a capsule that contains tiny beads and has the same coat. Which medication will act faster? Explain.arrow_forward7-22 If you add a piece of marble, CaCO3 to a 6 M HCI solution at room temperature, you will see some bubbles form around the marble as gas slowly rises. If you crush another piece of marble and add it to the same solution at the same temperature, you will see vigorous gas formation, so much so that the solution appears to be boiling. Explain.arrow_forwardWhen a mixture of hydrogen and bromine is maintained at normal atmospheric pressure and heated above 200. °C in a closed container, the hydrogen and bromine react to form hydrogen bromide and a gas-phase equilibrium is established. Write a balanced chemical equation for the equilibrium reaction. Use bond enthalpies from Table 6.2 ( Sec. 6-6b) to estimate the enthalpy change for the reaction. Based on your answers to parts (a) and (b), which is more important in determining the position of this equilibrium, the entropy effect or the energy effect? In which direction will the equilibrium shift as the temperature increases above 200. °C? Explain. Suppose that the pressure were increased to triple its initial value. In which direction would the equilibrium shift? Why is the equilibrium not established at room temperature?arrow_forward
- 7-17 If a certain reaction takes 16 h to go to completion at 10°C, what temperature should we run it if we want it to go to completion in 1 h?arrow_forwardWhich of the following describes the effect of raising the temperature of an exothermic reaction which has not yet reached equilibrium? a The rate of reaction slows and less product is produced b The rate of reaction slows, but more product is produced c The rate of reaction speeds up, but less product is produced d The rate of reaction speeds up and more product is producedarrow_forward16) HNO, H;SO,(catalyst) NH2arrow_forward
- Predict the products (using chemical formulas) of the following reaction. If there is more than 1 product separate them using a '+' sign. HBr + NaOH →arrow_forward8. Dopamine is a neurotransmitter (chemical messenger) between nerve cells. Deficiency of dopamine results in Parkinson's disease. Administration of dopamine does not stop the symptoms of this disease because dopamine in the blood cannot cross the blood-brain barrier. The drug Dopa, however, does give relief from Parkinson's symptoms. It can pass through the blood brain barrier and is converted by enzymes inside brain cells to dopamine: соон CH2CHNH2 HO ÇOOH но- CO2 HO HO -CH2CH2NH2 Dopa Dopamine This reaction is an example of @ acid - base reaction 6 addition 6. substitution @ eliminationarrow_forwardWhich of the following describes the effect of raising the temperature of an exothermic reaction which has not yet reached equilibrium? The rate of reaction slows and less product is produced. The rate of reaction slows, but more product is produced. The rate of reaction speeds up, but less product is produced. The rate of reaction speeds up and more product is produced.arrow_forward
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